FLUOROUS CATALYSIS Meaning and
Definition
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Fluorous catalysis refers to a type of catalytic reaction that takes place in fluorous solvents. A fluorous solvent is a unique type of liquid, typically a perfluorinated hydrocarbon, which is immiscible with many other commonly used organic solvents, such as water or organic solvents like benzene or toluene. Fluorous solvents possess several distinctive properties, such as low polarity, high thermal stability, and low toxicity, which make them valuable tools in synthesis and catalysis.
Fluorous catalysis involves the use of fluorous tags, which are fluorous moieties or groups attached to the catalyst or substrate. These tags enable the selective partitioning of the catalyst or substrate between the fluorous and non-fluorous phases, enabling separation and recycling of the catalyst. This property contributes to the high efficiency and sustainability of fluorous catalysis.
In a fluorous catalytic reaction, the fluorous catalyst interacts with the fluorous phase, while the non-fluorous reactants or substrates interact with the non-fluorous phase. The fluorous catalyst facilitates the reaction by enhancing the binding, activation, or transformation of the non-fluorous reactants or substrates. This selective interaction and partitioning of the fluorous catalyst allows for the acceleration of various chemical transformations, including but not limited to asymmetric synthesis, carbon-carbon and carbon-heteroatom bond formation, and oxidations.
Fluorous catalysis has gained significant attention in recent years due to its potential for greener and more sustainable chemical processes. By enabling efficient catalyst recovery and recycling, fluorous catalysis minimizes waste generation and reduces the environmental impact of chemical reactions.
Common Misspellings for FLUOROUS CATALYSIS
- dluorous catalysis
- cluorous catalysis
- vluorous catalysis
- gluorous catalysis
- tluorous catalysis
- rluorous catalysis
- fkuorous catalysis
- fpuorous catalysis
- fouorous catalysis
- flyorous catalysis
- flhorous catalysis
- fljorous catalysis
- fliorous catalysis
- fl8orous catalysis
- fl7orous catalysis
- fluirous catalysis
- flukrous catalysis
- flulrous catalysis
- fluprous catalysis
- flu0rous catalysis
Etymology of FLUOROUS CATALYSIS
The word "fluorous catalysis" is a combination of two terms: "fluorous" and "catalysis".
The term "fluorous" comes from the word "fluor", which refers to the element fluorine. This term is derived from the Latin word "fluere", meaning "to flow". "Fluorous" describes substances or materials that are highly fluorine-rich or containing fluorocarbon moieties. It signifies the ability of these substances to flow or be easily separated from non-fluorous materials.
The word "catalysis" is derived from the Greek term "katalysis", meaning "dissolution" or "loosening". It refers to the process of increasing the rate of a chemical reaction by the presence of a catalyst, which remains unchanged at the end of the reaction and enables the reaction to occur more easily or under milder conditions.
