"Microcanonical" is a term used in thermodynamics to describe a system in which the energy, volume, and number of particles are fixed. Its spelling is determined by its origin: "micro-" means small or very small, "canon" refers to a set of rules, and the suffix "-ical" denotes something related to a specific category. This is reflected in its phonetic transcription: /ˌmaɪkrəʊkəˈnɒmɪkəl/, with emphasis on the second and fourth syllables, and the pronunciation of "canon" as /ˈkanən/ instead of its usual /ˈkænən/.
The term "microcanonical" is an adjective used in the field of statistical mechanics and physics to describe a specific ensemble or system in thermodynamics. It refers to a system that is isolated from its surroundings, meaning it doesn't exchange any energy or particles with its environment. In this context, "microcanonical" is a state in which the total energy of the system is fixed or constant.
A microcanonical system is characterized by having a fixed number of particles, a constant volume, and a specific energy value. The energy value of the system is usually set by specifying the total energy within a certain range. The behavior of a microcanonical system is described by the laws of classical mechanics or quantum mechanics, depending on the scale of the system and the context of the study.
In statistical mechanics, the microcanonical ensemble is a mathematical framework used to describe the statistical properties of a system in equilibrium under the constraints mentioned above. It allows the calculation of various thermodynamic quantities such as entropy, temperature, and free energy. In this ensemble, all accessible microstates with the fixed energy are assumed to be equally likely, giving rise to the principle of equal a priori probabilities.
The concept of the microcanonical ensemble is particularly important in understanding systems where energy conservation is crucial or when studying isolated systems, such as isolated atoms, molecules, or small regions of the universe. By considering the microcanonical ensemble, physicists can analyze the statistical behavior and equilibrium properties of these systems.
The word "microcanonical" has its etymology rooted in the combination of two primary elements: "micro-" and "canonical".
"Micro-" is a prefix derived from the Greek word "mikros", meaning small or microscopic. It is often used to indicate something of a smaller scale or level of detail.
"Canonical" comes from the Greek word "kanon", which originally referred to a straight rod or ruler and later evolved to mean a rule or standard. Over time, it came to represent a fundamental principle or law accepted as authoritative or standard within a particular field or context.
When combined, "microcanonical" refers to a particular ensemble or statistical distribution used in statistical mechanics. It characterizes systems with fixed values of energy, particle number, and volume, for example. By emphasizing the "micro-" prefix, it highlights the specific focus on the detailed microscopic properties within a constrained context described by canonical principles.